Palladium-mediated base-free and solvent-free synthesis of aromatic azo compounds from anilines catalyzed by copper acetate
نویسندگان
چکیده
Abstract Herein, we report a new one-step direct synthesis of aromatic azo compounds from anilines under mild conditions. With the catalysis copper acetate mediated by palladium salt, rapid conversion to can be observed conditions base-free along with solvent-free. Furthermore, cross-coupling nitridation reaction based on this strategy was also studied. This research provides not only way for symmetrical and asymmetrical but platform exploring catalytic applications transition metal compounds.
منابع مشابه
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15 صفحه اولmelamine trisulfonic acid catalyzed regioselective nitration of aromatic compounds under solvent-free conditions
a simple, mild and efficient method for the regioselective nitration of various aromatic compounds usingpoly(4-vinylpyridinium nitrate) (p4vpyn) in the presence of melamine trisulfonic acid (mtsa), is reported.this method provides several advantages such as good selectiveity between ortho and para positions ofaromatic compounds, clean procedure, simple work-up, short reaction times, solvent-fre...
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ژورنال
عنوان ژورنال: Green Processing and Synthesis
سال: 2022
ISSN: ['2191-9542', '2191-9550']
DOI: https://doi.org/10.1515/gps-2022-0070